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The fact that you can move them manually suggests to me that you have permission and I believe with XP you have permission by default, Though it wouldn't hurt to open the properties of those drives and compare them for differences that mght seem applicable.
Another thought would be that perhaps in your backup program you have to set the parameters for what is to be backed up. Perhaps one drive is set to copy over anything newly created or modified, whereas the copy parameters for the other drive might be set to ignore modified files and just copy over new ones...Just a thought.
I'm not familiar with backup programs so I can't think of anything else to suggest.
Sam
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